Crystal structures of the first polymeric CuII complexes with thiosemicarbazone methyl pyruvate

نویسندگان
چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Predicting Polymeric Crystal Structures by Evolutionary Algorithmsa)

Qiang Zhu,1, b) Vinit Sharma,2, c) Artem R. Oganov,1, 3, 4 and Rampi Ramprasad2 Department of Geosciences, Stony Brook University, Center for Materials by Design, Institute for Advanced Computational Science, Stony Brook University, NY 11794, USA Materials Science and Engineering, Institute of Materials Science, University of Connecticut, Storrs, 06626, CT, USA Department of Problems of Physics...

متن کامل

Predicting polymeric crystal structures by evolutionary algorithms.

The recently developed evolutionary algorithm USPEX proved to be a tool that enables accurate and reliable prediction of structures. Here we extend this method to predict the crystal structure of polymers by constrained evolutionary search, where each monomeric unit is treated as a building block with fixed connectivity. This greatly reduces the search space and allows the initial structure gen...

متن کامل

X-Ray Crystal Structures of Discrete and Polymeric Chiral Silver Complexes of Monoterpenoid Alkenes

X-Ray crystal structures are reported for five silver(I) complexes of four monoterpenoid alkenes. Discrete mononuclear complexes of the chiral alkenes (1S)-(-)-α-pinene and (1S)(-)-β-pinene with silver perchlorate and silver hexafluorophosphate are described. The achiral diene γ-terpinene forms a discrete mononuclear adduct with silver hexafluorophosphate and a two-dimensional polymeric network...

متن کامل

Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template

Two dinuclear Cu complexes based on a diazecine ligand were characterized by X-ray diffraction, one of which includes the rare Cu–F bond, resulting from dissociation of a BF4 ion. The F ligands actively participate in the crystal structure, behaving as acceptors for hydrogen bonding.

متن کامل

Engineering coordination assemblies of dinuclear CuII complexes.

Hybrid organic-inorganic coordination assemblies are synthesized using modified aminocarboxylic acid ligands as the structure-directing agents. The synthetic approach results in two novel dinuclear copper(II) complexes, K2[CuII(hnida)]2.2H2O (1) and K4[CuII(chnida)]2.4H2O.4MeOH (2) that assemble in the presence of suitable counterions into a densely packed hexagonal array or an open-framework s...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Acta Crystallographica Section A Foundations and Advances

سال: 2019

ISSN: 2053-2733

DOI: 10.1107/s2053273319093318